Pteridium is dangerous stuff....dont know if what you are experiencing is an allergic reaction to plant material impregnated in your gloves??
check out the following link for more info Biological Flora of the British Isles: Pteridium aquilinum (L.) Kuhn - MARRS - 2006 - Journal of Ecology - Wiley Online Library the following is taken straight off the site:
For humans the health significance of Pteridium poisoning is potentially considerable. In Japan, Brazil, and across northern America (especially the Appalachians), Pteridium is consumed as the developing frond, i.e. the crozier or ‘fiddlehead’ (Fig. 7f). At this developmental stage the quantities of toxin are at a maximum, and in Japan there is the highest incidence of gastric tumours in the world (Evans 1976a; Marlière et al. 2000). High levels of gastric cancers have been identified in other areas where there are large Pteridium infestations, e.g. Costa Rica and North Wales (Buckley 1989; Villalobos-Salazar et al. 1989), although transfer pathways and causal relationships have not been proven. Some effects can be transmitted experimentally via milk (Evans et al. 1972; Villalobos-Salazar et al. 1990; Alonso-Amelot et al. 2000). Transfer to humans through drinking water has also been investigated, and although water soluble extracts of Pteridium contain carcinogens, Galpin & Smith (1986) thought this is not a major cause for concern. However, more recently Rasmussen et al. (2003a,b) has detected ptaquiloside throughout the plant–soil system in Denmark (e.g. 108–3795 µg g−1 in fronds, 213–2145 µg g−1 in rhizomes, 200–8500 µg g−1 in soil solutions). This chemical is water soluble and easily leached from fronds and they estimated a flux of 260 mg m−2 transferred to soils. These fluxes were considered a potential risk for the contamination of groundwater supplies, especially on sandy soils.
regards
Dave